Yes sorry, probably not very clear there.
Video>Capture Filter to PAL_B ?? Might need to try _G
Video>capture PIN> Output size will probably be stuck on 320x240. Leave it.
Video>Set Custom Format to 720x576.
Finger's crossed on the audio sync! From what I've read, it depends to a certain degree on the capture card/stick. AmarecTV is a fallback if VDub captures are out of sync (or you can't stretch the audio in your video editor).
You haven't mentioned what video codec you're using; I suggest Lagarith or
HUFFYUV. Your captures will then be lossless but not massively huge file sizes (Lag and Huff are about 40gb per hour), "uncompressed" is 5 times that IIRC.
There used to be a very good, detailed guide for capturing with VDub on this site by Sanlyn but I can't find it at the moment.